The Three Devs and a Maybe podcast has been around since the end of last year and has posted some great episodes on a wide variety of topics, including several shows related to PHP. Some of their current shows include:

• Getting Started (in PHP)
• Advice to new PHP web developers
• Introduction to object-oriented programming
• Using Composer and the Command Line (CLI)

Check out the podcast and the past episodes and be sure to subscribe to their feed if you enjoy the show!