On the KillerPHP.com site there's a new post from Stefan Mischook where he suggests that PHP is the first language you should learn if you're new to development.
Anyone who reads my stuff knows that if I am anything, I am practical. So when it comes to learning (and teaching) programming to someone new to the whole programming game, for several pragmatic reasons, I think PHP by far is the best language to begin with. Here are some of the reasons: it is easy to learn, it is the most popular web scripting language and it is fast to program with.
He shares these thoughts and a few more in a short video (or here on YouTube).